Octane rating
True that ethanol raises the octane but octane is really a product of the refining or distilling process;
"4. Reforming
Octane rating is a key measurement of how well a gasoline performs in an automobile engine. Much of the gasoline that comes from the Crude Units or from the Cracking Units does not have enough octane to burn well in cars.
The gasoline process streams in the refinery that have a fairly low octane rating are sent to a Reforming Unit where their octane levels are boosted. These reforming units employ precious-metal catalysts – platinum and rhenium – and thereby get the name “rheniformers.” In the reforming process, hydrocarbon molecules are “reformed” into high octane gasoline components. For example, methyl cyclohexane is reformed into toluene."
From the horse's mouth.
Processing & Refining Crude Oil | What We Do | About the Refinery
BossHogg:
I am new to the Ram Forum - please excuse any text entry missteps - this entry/text editor is clunky.
I appreciate the technical reference to octane from the refiners perspective. However, I disagree that "octane is really a product of the refining or distilling process".
"Octane" (RM/2 and RON) is a measurement of "resistance to knock" (Knock = premature combustion during the compression stroke of the Otto cycle in spark ignition engines). This attribute of the fuel does not only come from catalytic reforming at a petroleum refinery - that is merely one method to produce high octane products. I will concede FCC units are common but because they have high costs to operate (high cost catalyst), it is often optimized/ reduced/ minimized as much as possible, where possible.
Blending to increase octane is the primary method of octane lift used in the US gasoline pool. (Lift = A base stock of naphtha or natural gasoline at 77 to 81 octane, taken up to finished gasoline at 87-94). Mixing in lower cost products introduces a market based incentive to find low cost octane sources such as ethanol or butane - neither coming from refineries. Market forces cause refiners to blend the lowest cost admixtures to produce an on spec product. While this process currently is primarily ethanol and butane, this also allows for BTX or other aromatics you reference.
Blending to achieve octane lift makes ethanol a great solution and is why it is so popular globally as an octane booster...it is simply dirt cheap octane without the environmental load you get from MTBE and BTX.
Importantly, nearly all gasoline produced in the US is coming off the back-end of the refinery between 82 & 87 octane, as an unfinished product known as CBOB or RBOB (
Conventional
Blendstock for
Oxygenate
Blending or Refined... for RFG markets). These "BOB's" are engineered to have ethanol added explicitly to increase the octane rating.
Induced by legislation (EISA 2007), refiners have recognized this thermodynamic economic logic and configured FCC units such that they can only produce suboctane that requires ethanol to make spec.
Long winded but... octane can come from a couple of places.