If you're not going to be towing heavy loads, I'd go with the 3.6L.
I'm on my second Ram lease with the 3.6 V6 engine. Since it's a business lease vehicle I was cost conscious the first time around. Previously I had seven Ford F150 leases--all had V8's--and was sick and tired of 14-15 mpg, which is why I got a Ram with a V6. Once I got my 2015 Ram I was astounded to find I was getting 20 mpg overall in 80% city, 20% highway driving. This Ram with the V6 also accelerated at least as fast as my previous F150 XLT with the 5.0L engine.
During this first lease my Ram needed a new thermostat so I had a Ram with a hemi as a loaner for a couple of days. Yeah, it was fun tromping on the gas going down freeway ramps a couple of times, but after I got my jollies doing that I reset the EVIC and found when I turned in the vehicle I was getting 14 mpg (overall) driving my usual workaday paths around town. No, thank you.
When my lease was nearing its end I was searching for another Ram and I couldn't find what I wanted in a V6, so I started looking at hemis. First of all, the hemi is a $1,495 option. Then there is $500 for the upgraded transmission. So, $2,000 more for the entrance fee.
Now figure over 12,000 miles per year, the V6 would use 600 gallons of gas whereas the hemi would use 800 gallons. At $2.50 a gallon that is an extra $500 per year in gasoline. For me, I didn't like those numbers. I eventually found a V6 that I liked and leased it.