Just stumbled on this. As I understand it, taken from the FSM. Likely this can be confirmed by Forum members with access to FCA FSM.
Bold below is mine for emphasis.
"48 Volt Wiring Component Index The 48 volt wiring is in line from the MGU to the PPU and to the PDC. The wiring has the 48 volt connection and the 12 volt connections. The PPU will convert the 48 volt power in and 12 volt power out to the 12 volt system main battery.
In the event that the 12 volt system battery is discharged completely, the PPU will provide the voltage to allow the system to start. Once the vehicle is started, the system will charge up the 12 volt battery and allow for the battery to take a charge."
From a July 20, 2020 post on another forum. Hope I am not ******** up, by posting this. Certainly NOT promoting another forum, simply posting requested information.
https://**************/community/attachments/e-torque-from-fsm-pdf.62640/
System would not let me post PDF directly. (Or I am not smart enough to do so.)
EDIT. Appears I did scr*w up. Apologies to owners, system... Livin and learnin here.