It's controversial but the owners manual trumps all and should always be what is followed.
I have posted that video in other like discussions and some think they do not know what they are talking about but I personally believe the guy that 5W-30 was used and for whatever reason, a last minute change to the 0W-40 spec in the manual was made.
I have had oil analysis of both the factory fill and two oil changes with the Ultra 0W-40 and find it is on the lower end of the 40W scale and shears down into a thick 30W in use. So that makes me believe they did use 5W-30 and found it satisfactory.
The main thing with Pennzoil MS-12633 and even the AMSOIL offering claiming to meet MS-12633, is that these oils are higher in molybdenum when compared to standard 5W-30. So there is some technical reason for it.
In some threads showing cam failures on the 5.7 Hemi, a common theme was the use of low or no molybdenum oils like Valvoline were exclusively used before the failures. I think the high moly content of the MS-12633 0W-40 oils is to alleviate that issue with the 6.4. That is just speculation on my part though.
Once I am out of warranty, I will probably migrate to a 5W-30 synthetic oil but it will be one with a decent moly content.