So the 2014 5.7 hemi's come with synthetic or conventional oil getting ready to do a oil change soon and I bought the truck used have no idea what's in it?
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Well for The factory fill it has been assumed it is PYB conventional. Being used and the fact that you don't know what's in it I would do a UOA on the current oil that is in it. It will give you a really good idea of how well it was taken care of.
Regardless, use whatever oil you want as far as conventional or synthetic, but we on this thread will definitely recommend synthetic first.
We will not tell you what to use but we would also recommend One of these top few choices (IMO all in 5w30, but that is just IMO, no it won't hurt your MDS) even though there are other good ones
Redline
Amsoil
Pennzoil ultra Platinum
Pennzoil platinum
Shchaeffers
As i said. There are others but these are some good ones.
EDIT:
Just note that we always lean towards oil that has high moly & zddp just to help prevent or or even stop the hemi tick and for excellent engine protection on to of that.