If your lithium battery came with a BMS then they will not overcharge. The alternator is only going to see the batteries as a load and will continue to put out amps up to its rated capacity. I have 2 100 AH lithium batteries on my RV and I use the standard 7 pin plug and never had a issue with my alternator overheating. Like someone else said the 7 pin does not put out enough amperage to cause a issue with your alternator. The DC to DC converter is used if you want to charge a low charged RV battery as they usually have a larger cable direct from the battery to supply more amperage. If you are worried of low battery capacity when boondocking, then get a solar panel and solar controller, they will charge your batteries on they way to the campground and will continue charging when disconnected from the truck.