Aren't all PCVs vented into the intake?
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Under smog control most are, but with the Hemi's higher compression and the common use today of shorter piston skirts and fewer piston rings, the Hemi produces a lot of blow-by compared to your typical six-banger, or engine with a flatter combustion chamber.
That blow-by winds up in the crankcase as oil vapor, some water vapor and combustion by-products including unburned fuel. The PCV uses vacuum from the intake manifold to suck all that nasty stuff out and then burn it off in the engine.
That stuff is no-bueno as fuel.
In addition to oiling up your intake over time it is of inconsistent composition introducing irregular combustion. Normal combustion is the burning (not "exploding") of a fuel and air mixture--it should burn in an even fashion across the chamber, with ignition originating at the spark plugs (2) and progressing across the chamber in a three dimensional fashion. Similar to a pebble in a pond, the flame front should progress in an orderly fashion. The burn moves all the way across the chamber and, quenches (cools) against the walls and the piston crown. The burn should be complete with no remaining fuel-air mixture. Detonation occurs when air and fuel that is ahead of the flame front ignites before the flame front arrives because the flame front is irregular. This combustion is uncontrolled and sporadic and can produce a pinging noise when the conditions become worse—except today you really can’t hear it in the cab through all the sound deadening materials.
Higher octane fuel burns more controllably and is less likely to combust before the flame front. Uneven combustion (detonation) occurs for a number of reasons, increased compression, high temperatures, lean fuel/air mixture, advanced ignition timing, and lower octane levels.
Entrained oil vapor from the PCV will lower the octane within the fuel air mixture while also effectively leaning your fuel mixture and preventing smooth flame front progression across the chamber.
Engine designers use test data to determine how much compression an engine can have and run at the optimum spark advance (objectively 14 degrees BTDC). The design compression ratio is adjusted to maximize efficiency/power using the
anticipated fuel octane, and fuel air mix . Contamination from the PCV is
anticipatable. Entrained oil and potentially water vapor can degrade combustion, leading to detonation. One of the most common adjustments to restore maximum performance without detonation is to retard the ignition timing, and that’s what the PCM does. Given the known introduction of combustion inhibitors by the PCV, the engine designers simply decided the way to ensure a stock engine would avoid detonation and achieve optimum timing for the Hemi's compression ratio was to specify a preference for a higher octane fuel.
A final option is the oil catch can which ensures the fuel air mixture is consistent, even with lower octane fuel, by preventing combustion interfering PCV dredge from entering the combustion chamber.
I admit, if I were so inclined, I wouldn't go stop light hustling with 87, but for around town, I get plenty of zip, and you only have to smell the nasty in the catch can to know that stuff is no-bueno for combustion.
Okay, got my catcher's gear on waiting for the spitballs from the catch can haters....!