If your engine is putting that much "oil into your catch can in. Week, I think you have bigger problems.
I am definitely in the boat that it can't hurt. But I think the octane claims are a little stretched. If I burn 100 litres of fuel a week, and my catch can collects 250 mls, or about a cup (which is really high) and we assume that oil has zero octane, it would drop the octane level from 87 to 86.78. But oil burns and therefore has an octane greater than zero.
Just like with cold air intakes, throte body spacers, etc. adding a catch can will have no impact on daily driving. There could be long term reliability benefits, but I don't know if that's been proven yet or not. I would like to see an independent lab put a few of these motors on a test stand some with catch cans and some without, run them for 100,000 miles and rip the engine apart to see where things stand.